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Thanks to the unique molecular fingerprints in the mid-infrared spectral region, absorption spectroscopy in this regime has attracted widespread attention in recent years. Contrary to commercially available infrared spectrometers, which are limited by being bulky and cost-intensive, laboratory-on-chip infrared spectrometers can offer sensor advancements including raw sensing performance in addition to utilization such as enhanced portability. Several platforms have been proposed in the past for on-chip ethanol detection. However, selective sensing with high sensitivity at room temperature has remained a challenge. Here, we experimentally demonstrate an on-chip ethyl alcohol sensor based on a holey photonic crystal waveguide on silicon on insulator-based photonics sensing platform offering an enhanced photoabsorption thus improving sensitivity. This is achieved by designing and engineering an optical slow-light mode with a high group-index ofn_g = 73 and a strong localization of the modal power in analyte, enabled by the photonic crystal waveguide structure. This approach includes a codesign paradigm that uniquely features an increased effective path length traversed by the guided wave through the to-be-sensed gas analyte. This PIC-based lab-on-chip sensor is exemplary, spectrally designed to operate at the center wavelength of 3.4 μm to match the peak absorbance for ethanol. However, the slow-light enhancement concept is universal offering to cover a wide design-window and spectral ranges towards sensing a plurality of gas species. Using the holey photonic crystal waveguide, we demonstrate the capability of achieving parts per billion levels of gas detection precision. High sensitivity combined with tailorable spectral range along with a compact form-factor enables a new class of portable photonic sensor platforms when integrated with quantum cascade laser and detectors.

 

Abstract With success of silicon photonics having mature to foundry-readiness, the intrinsic limitations of the weak electro-optic effects in Silicon limit further device development. To overcome this, heterogeneous integration of emerging electrooptic materials into Si or SiN platforms are a promising path to deliver <1fJ/bit device-level efficiency, 50+Ghz fast switching, and <10's um^2 compact footprints. Graphene's Pauli blocking enables intriguing opportunities for device performance to include broadband absorption, unity-strong index modulation, low contact resistance. Similarly, ITO has shown ENZ behavior, and tunability for EOMs or EAMs. Here we review recent modulator advances all heterogeneously integrated on Si or SiN such as a) a DBR-enabled photonic 60 GHz graphene EAM, b) a hybrid plasmon graphene EAM of 100aJ/bit efficiency, d) the first ITO- based MZI showing a VpL = 0.52 V-mm, and e) a plasmonic ITO MZI with a record low VpL = 11 V- um. We conclude by discussing modulator scaling laws for a roadmap to achieve 10's aJ/bit devices.